Faculty

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Joel Mague, Professor
Director, X-ray Crystallography Laboratory
Ph.D., 1965, MIT
Office: 5018 Percival Stern Building
Telephone: (504) 862-3585
Email: joelt@tulane.edu

Discipline:
Inorganic Chemistry

Areas of current interest include:
Research efforts in our group revolve around using lasers to initiate and study chemistry. A variety of lasers are employed to investigate problems in areas ranging from gas-phase Doppler spectroscopy to laser-assisted thin-film growth. Mass spectrometers are used extensively for product detection, but materials characterization methods such as x-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) are enjoying increasing popularity within our group.

Selected Publications

B Punji, JT Mague, MS Balakrishna, Highly air-stable anionic mononuclear and neutral binuclear palladium(II) complexes for C-C and C-N bond-forming reactions Inorganic Chemistry, 46 (26), pp. 11316-11327 (2007).   

B Punji, JT Mague, MS Balakrishna, Thioether-functionalized ferrocenyl-bis(phosphonite), Fe{(C5H4)P(-OC10H6(μ-S)C 10H6O-)}2: Synthesis, coordination behavior, and application in Suzuki-Miyaura cross-coupling reactions, Inorganic Chemistry, 46 (24), pp. 10268-10275 (2007).  

P Chandrasekaran, JT Mague, Venkateswaran, R., Balakrishna, M.S.
Cyclodiphosphazane cis-{(o-MeOC6H4O)P(μ-NtBu)} 2 as a bridging bidentate ligand: Synthesis, structures of heterometallic complexes, and halogen exchange between Rh-Cl and Cu-X (X = Br, I), European Journal of Inorganic Chemistry, (31), pp. 4988-4997 (2007).

Y Ling, JT Mague, AE Kaifer, , Inclusion complexation of diquat and paraquat by the hosts cucurbit [7] uril and cucurbit [8] uril, Chemistry - A European Journal, 13 (28), pp. 7908-7914 (2007). 

MS Balakrishna, JTMague, Synthesis and molecular structure of 1,3-di-tert-butyl-2,4- bis(cyclodipentadienyl)iron(II) 1,3,2,4-diazadiphosphetidine, [Fe(η5-C5H4)2(PN tBu)2], Organometallics, 26 (18), pp. 4677-4679 (2007).  

H Murata, JT Mague, S Aboaku, N Yoshioka, PM Lahti, P.M, An organic radical solid solution with strong ferromagnetic exchange, Chemistry of Materials, 19 (17), pp. 4111-4113 (2007).  

I Medina, H, Jacobsen, JT Mague,  M J Fink,Dicoordinate copper(I) silanechalcogenolates, Inorganic Chemistry, 45 (22), pp. 8844-8846 (2006).   

J Pang, L Yang, DA Loy, H Peng, HS Ashbaugh, JT Mague, CJ Brinker, Y Lu,  Mesoscopically ordered organosilica and carbon-silica hybrids with uniform morphology by surfactant-assisted self-assembly of organo bis-silanetriols, Chemical Communications, (14), pp. 1545-1547 (2006).

M Pattabiraman, A Natarajan, R Kaliappan, JT Mague, V Ramamurthy, Template directed photodimerization of trans-1,2-bis(n-pyridyl)-ethylenes and stilbazoles in water, Chemical Communications, (36), pp. 4542-4544 (2005).  

A Natarajan, JT Mague, V Ramamurthy, Asymmetric induction during Yang cyclization of α-oxoamides: The power of a covalently linked chiral auxiliary is enhanced in the crystalline state, Journal of the American Chemical Society, 127 (10), pp. 3568-3576 (2005).  

S Priya, MS Balakrishna, and JT Mague, First Example of a Heptacyclic Tetranuclear,
Five- and Six-coordinate Titanium Complex [{iPrO)2Ti(m3-O)(TiCl(iPrO)((OC6H4)2PPh)}2],
Chemistry Letters, 33, 308 (2004).

RC Boyle, JT Mague, and MJ Fink, cis-Dichloro(N,N,N',N'-tetramethyl-1,2-
diaminoethane)palladium(II), Acta Cryst., E60, m40, (2004).

RC Boyle, JT Mague, and MJ Fink, m-1,2-Bis(dicyclohexylphosphino)ethane-k2P:P'-
bis{[1,2-bis(dicyclohexylophosphino)ethane-k2P,P']palladium(0)}, Acta Cryst., E60, m625, (2004).

JT Mague, WL Alworth, and FL Payton, Curcumin and Derivatives, Acta Cryst., C60, o608 (2004).

MS Balakrishna, PP George and JT Mague, Synthesis and Single Crystal X-ray Structure
of N,N'-bis(diphenylphosphino)piperazine", J. Chem. Research (S), 576 (2003).

MS Balakrishna, R Panda and JT Mague, Synthesis, Structures, Spectroscopic and
Electrochemical Studies of Ru(II) Complexes Containing Bis(phosphino)amine
Ligands. Crystal and Molecular Structures of trans-RuCl2{Ph2PN(Me)-PPh2-κP,κP}2 and
trans-[RuCl2{Ph2PN(iPr)PPh2-κP,κP}2, Polyhedron, 22, 587 (2003).

S Priya, MS Balakrishna, JT Mague and SM Mobin, Insertion of Carbon Fragments into
P(III)-N Bonds in Aminophosphines and Aminobis (phosphines): Synthesis, Reactivity and
Coordination Chemistry of Resulting Phosphine Oxide Derivatives. Crystal and Molecular
Structures of (Ph2P(O)CH2)2NR (R = Me, nPr, iPr, nBu), Ph2P(O)CH(OH)nPr and
cis-[Mo(O)2{(Ph2P(O)CH2)2NEt-kO, kO}], Inorg. Chem. 42, 1272 (2003).

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